A Study on the [3+2] Cycloaddition Reaction of Square Planar Ni(II) Azido Complexes: Structure, Properties, and Catalytic Applications of the Products.
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DOI: 10.1021/acs.inorgchem.5c01111
Abstract: Two square planar Ni(II) azido complexes [Ni(N3)(L1)] and [Ni(N3)(L2)] (where L1 = N-phenyl-2-(pyridin-2-ylmethylene)hydrazine-1-carbothioamide; L2 = (E)-1-(((2-(diethylamino)ethyl)imino)methyl)naphthalen-2-olato) were used to study the effect of auxiliary ligands on the [3+2] cycloaddition reactions with different dipolarophiles. The reactivity… read more here.
Keywords: reaction; cycloaddition reaction; square planar; planar azido ... See more keywords
Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of 4-Benzoylpyridine
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DOI: 10.3390/sym13112026
Abstract: The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]; 1, [Ni(4bzpy)4(N3)2]; 2 and [Zn(4bzpy)2(N3)2]n; 3 with 4-benzoylpyridine (4bzpy) were presented. All complexes contain hexa-coordinated divalent metal ions with a slightly distorted octahedral MN6… read more here.
Keywords: azido; molecular supramolecular; azido complexes; combined hirshfeld ... See more keywords