Azine-N-oxides as effective controlling groups for Rh-catalysed intermolecular alkyne hydroacylation
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DOI: 10.1039/d1sc03915f
Abstract: Heterocycle-derived aldehydes are challenging substrates in metal-catalysed hydroacylation chemistry. We show that by using azine N-oxide substituted aldehydes, good reactivity can be achieved, and that they are highly effective substrates for the intermolecular hydroacylation of… read more here.
Keywords: oxides effective; effective controlling; azine; controlling groups ... See more keywords
Sustainable Synthesis of Heteroaryl Ethers from Azine N-Oxides via Phosphoramide Catalysis
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DOI: 10.1039/d5gc00249d
Abstract: A rapid and eco-friendly approach has been devised for synthesizing heteroaryl ethers. This methodology involves the reaction between nitrogen heteroaromatic N-oxides and phenol derivatives or alcohols, catalyzed by an in... read more here.
Keywords: heteroaryl; sustainable synthesis; synthesis heteroaryl; azine oxides ... See more keywords