Aziridine Group Transfer via Transient N-Aziridinyl Radicals
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DOI: 10.1021/jacs.4c14169
Abstract: Aziridines are the smallest nitrogen-containing heterocycles. Strain-enhanced electrophilicity renders aziridines useful synthetic intermediates and gives rise to biological activity. Classical aziridine syntheses—based on either [2 + 1] cycloadditions or intramolecular substitution chemistry—assemble aziridines from acyclic… read more here.
Keywords: group transfer; chemistry; aziridine group; aziridinyl radicals ... See more keywords