Spectroscopic characterization, structural investigation, DFT study, and Hirshfeld surface analysis of rhodium and ruthenium amido azo complexes
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DOI: 10.1016/j.molstruc.2021.130671
Abstract: Abstract The reaction of 2,2′-diaminoazobenzene, (H2L) [where H represents the dissociable amino protons], with RhCl3 and Ru(dmso)4Cl2 separately afforded the new homoleptic mononuclear amido azo complexes [Rh(HL)2]Cl (1) and [Ru(HL)2](ClO4)2 (2), respectively. Complex 1 &… read more here.
Keywords: amido azo; surface analysis; hirshfeld surface; azo complexes ... See more keywords