No Switching Cooperativity between Coordinated Azo Ligands on Complexes Having {MII(phosphane-κ2P)}2+ (M = Pd, Pt) Scaffolds
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DOI: 10.1021/acs.inorgchem.4c02169
Abstract: A series of square-planar palladium and platinum compounds with cis-blocking phosphanes and terminal azobenzene ligands [M(dppp)(azo)2](OTf)2 (azo = CN(C6H4)-N=N-(C6H4)CN (iso-cyano), CN(C6H4)-N=N-(C6H5) (iso-Ph)) and [{M2(tpbz)}(azo)4](OTf)4 (azo = CN(C6H4)-N=N-(C6H5) (iso-Ph)) have been synthesized and fully characterized. Similarly… read more here.
Keywords: coordinated azo; azo ligands; switching cooperativity; c6h4 ... See more keywords