Thermal Half-Lives of Azobenzene Derivatives: Virtual Screening Based on Intersystem Crossing Using a Machine Learning Potential
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DOI: 10.1021/acscentsci.2c00897
Abstract: Molecular photoswitches are the foundation of light-activated drugs. A key photoswitch is azobenzene, which exhibits trans–cis isomerism in response to light. The thermal half-life of the cis isomer is of crucial importance, since it controls… read more here.
Keywords: machine learning; thermal half; azobenzene derivatives; lives azobenzene ... See more keywords
Green-Light-Triggered Phase Transition of Azobenzene Derivatives toward Reversible Adhesives.
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DOI: 10.1021/jacs.9b01056
Abstract: Studies on the azobenzene derivative based phase transitions mostly rely on photoisomerization, which require a long time to spontaneously revert back. Here we show a photothermal-driven solid-to-liquid transition and fast reversion of azobenzene derivatives. Owing… read more here.
Keywords: transition; green light; reversible adhesives; azobenzene ... See more keywords
Two azobenzene derivatives CAB/ACB as reusable sunscreen: UV absorptive capacity and biosafety evaluation
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DOI: 10.1039/c7ra10290a
Abstract: Exposure to UV radiation may cause harmful effects to the skin such as damage, aging and cancer, which can be prevented by using sunscreens. Here, two azobenzene derivatives, 4-cholesterocarbonyl-4′-(N,N,N-triethylaminebutyloxyl bromide) azobenzene (CAB) and 4-cholesterocarbonyl-4′-(N,N-diethylaminebutyloxyl) azobenzene… read more here.
Keywords: two azobenzene; capacity; reusable sunscreen; cab acb ... See more keywords