LAUSR

Azobenzenyl Calcium Complex: Synthesis and Reactivity Studies of a Ca(I) Synthon.

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1 Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03008

Abstract: Attempted preparation of a low-valent Ca(I) complex by reduction of Ca iodide precursor [LCaI(THF)]2 (1) (L = [CH3C(NAr)CHC(CH3)NCH2CH2N(CH3)2]-, Ar = 2,6-iPr2C6H3), with KC8 led to isolation of a dinuclear calcium azaallyl complex {[H2CC(NAr)CHC(CH3)(NCH2CH2N(CH3)2)]Ca(THF)}2 (2). Alternatively,… read more here.

Keywords: thf; calcium; azobenzenyl calcium; ch3 ... See more keywords