Reaction of hydroxyamide-functionalized azolium salt with Ag2O: Three different transformations
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121556
Abstract: Abstract We report three different transformations in the reaction of the hydroxyamide-functionalized azolium chloride 1 with Ag2O. These transformations were controlled by the N-substituent at the azolium ring of 1. Treatment of 1c (R = Me, alkyl)… read more here.
Keywords: reaction hydroxyamide; azolium; reaction; different transformations ... See more keywords
Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12845
Abstract: Photoinduced hydrogen atom transfer (HAT) has been developed as a powerful tool to generate synthetically valuable radical species. The direct photoexcitation of ketones has been known to promote HAT or to generate acyl radicals through… read more here.
Keywords: azolium; hydrogen atom; atom transfer;