Vitamin B12 and Micellar Solution Enable Regioselective Ring Opening of Epoxides and Aziridines with Electrophilic Olefins
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DOI: 10.1021/acs.orglett.5c01376
Abstract: Vitamin B12, a water-soluble cobalt complex, is inherently predisposed to catalyze reactions under aqueous conditions. Despite its potential, adopting this strategy for transformations of hydrophobic reagents has been challenging, because of their low aqueous solubility.… read more here.
Keywords: micellar solution; electrophilic olefins; b12 micellar; aziridines electrophilic ... See more keywords