Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for gem-difluoroolefin synthesis.
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DOI: 10.1039/c7cc04377e
Abstract: Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the C[double bond, length as m-dash]C bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were… read more here.
Keywords: gem; bond; bond cleavage; b12 tio2 ... See more keywords