Cubic Fd3¯c Ba8{Ni,Mn}4[BP3O11(OH)2]4 with anionic units of four-octahedral clusters and four borophosphate groups embedded into Ba-cations medium
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DOI: 10.1016/j.solidstatesciences.2019.106013
Abstract: Abstract Single crystals of new high symmetrical borophosphate, Ba8{Ni2+0.7Mn2+0.2Fe3+0.014⎕0.086}4⋅[BP3O10.9(OH)2.1]4, sp.gr. Fd 3 ¯ c, a = 25.36 A, are synthesized in multi-component hydrothermal systems. It is large inorganic structure with the anionic part, characterized as a complex unit… read more here.
Keywords: octahedral clusters; borophosphate; borophosphate groups; ba8 ... See more keywords