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Published in 2025 at "Advanced Materials"
DOI: 10.1002/adma.202505444
Abstract: Reported here is the synthesis of stretchable hydrogels with large spherulites of different morphologies by polymerization‐induced crystallization of dopant molecules. By varying the concentrations of chemical crosslinker and initiator, or the light intensity for photopolymerization,…
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Keywords:
crystallization;
luminescence;
banded spherulites;
stretchable hydrogels ... See more keywords
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Published in 2019 at "Colloid and Polymer Science"
DOI: 10.1007/s00396-019-04503-8
Abstract: By crystallization of poly–ε–caprolactone (PCL) at temperatures (55 ∘C ≥ Tc ≥ 50 ∘C) close to the melting point (Tm = 61 ∘C), banded spherulites form. These structures show a periodicity of P = 32 µm as determined…
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Keywords:
non banded;
banded spherulites;
poly caprolactone;
microscopy ... See more keywords
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Published in 2019 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.9b00416
Abstract: Chiral silica, which acts as a nucleating agent of poly(e-caprolactone) (PCL), was demonstrated to induce excess handedness of lamellar twist in the banded spherulites of PCL blended with poly(viny...
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Keywords:
twist banded;
handedness lamellar;
lamellar twist;
banded spherulites ... See more keywords
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Published in 2024 at "Polymers"
DOI: 10.3390/polym16172411
Abstract: The decades-long paradigm of continuous and perpetual lamellar twisting constituting banded spherulites has been found to be inconsistent with several recent studies showing discontinuity regions between consecutive bands, for which, however, no explanation has been…
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Keywords:
mechanism banded;
polymers transcrystalline;
banded spherulites;
mechanism ... See more keywords