Visible Light-Driven Interrupted Barton Reaction: Intermolecular Radical-Relay Sulfonyloximation of Alkenes with DABSO and Alkyl Nitrites.
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DOI: 10.1021/acs.orglett.4c04257
Abstract: A visible light-driven, intermolecular interrupted Barton reaction has been developed for radical-relay sulfonyloximation of alkenes with alkyl nitrites, using DABSO as a trapping reagent. This method overcomes the challenges of competing normal Barton reactions and… read more here.
Keywords: barton reaction; visible light; interrupted barton; barton ... See more keywords