Direct Base-Assisted C‒H Cyclonickelation of 6-Phenyl-2,2′-bipyridine
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DOI: 10.3390/molecules25040997
Abstract: The organonickel complexes [Ni(Phbpy)X] (X = Br, OAc, CN) were obtained for the first time in a direct base-assisted arene C(sp2)–H cyclometalation reaction from the rather unreactive precursor materials NiX2 and HPhbpy (6-phenyl-2,2′-bipyridine) or from… read more here.
Keywords: direct base; base assisted; base; phenyl bipyridine ... See more keywords
A Concise Approach to N-Substituted Rhodanines through a Base-Assisted One-Pot Coupling and Cyclization Process
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DOI: 10.3390/molecules25051138
Abstract: An efficient approach to obtain functionalized rhodanines was developed through a base-assisted one-pot coupling and continuous cyclization of a primary amine, carbon disulfide, and methyl (2-chloroacetyl)carbamate. This conversion tolerates a broad range of functional groups… read more here.
Keywords: substituted rhodanines; base assisted; assisted one; one pot ... See more keywords