Articles with "base bifunctional" as a keyword



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Nanosized Ti-Based Perovskite Oxides as Acid–Base Bifunctional Catalysts for Cyanosilylation of Carbonyl Compounds

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Published in 2023 at "ACS Applied Materials & Interfaces"

DOI: 10.1021/acsami.3c01629

Abstract: The development of effective solid acid–base bifunctional catalysts remains a challenge because of the difficulty associated with designing and controlling their active sites. In the present study, highly pure perovskite oxide nanoparticles with d0-transition-metal cations… read more here.

Keywords: base bifunctional; acid base; carbonyl compounds; bifunctional catalysts ... See more keywords

Construction of acid-base bifunctional covalent organic frameworks via Doebner reaction for catalysing cascade reaction.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d1cc06461d

Abstract: We report herein a series of quinoline-4-carboxylic acid linked COFs via the multicomponent one-pot in situ Doebner reaction. The obtained acid-base bifunctional COFs are chemically stable and can highly promote one-pot cascade deacetalization-Knoevenagel condensation reaction… read more here.

Keywords: doebner reaction; reaction; base bifunctional; acid base ... See more keywords
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Thermally activated bipyridyl-based Mn-MOFs with Lewis acid-base bifunctional sites for highly efficient catalytic cycloaddition of CO2 with epoxides and Knoevenagel condensation reactions.

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Published in 2023 at "Dalton transactions"

DOI: 10.1039/d3dt00043e

Abstract: Metal-organic frameworks (MOFs) have become preferred heterogeneous catalytic materials for many reactions due to their advantages such as porosity and abundant active sites. Here, a 3D Mn-MOF-1 [Mn2(DPP)(H2O)3]·6H2O (DPP = 2,6-di(2,4-dicarboxyphenyl)-4-(pyridine-4-yl)pyridine) was successfully synthesized under… read more here.

Keywords: knoevenagel condensation; based mofs; base bifunctional; acid base ... See more keywords