Lewis Base-Boryl Radicals Enabled the Desulfurizative Reduction and Annulation of Thioamides.
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DOI: 10.1021/acs.orglett.7b03201
Abstract: A new protocol for radical transformations of thioamides promoted by Lewis base-boryl radicals is reported. The desulfurizative reduction to access organic amines was enabled utilizing 4-dimethylaminopyridine-BH3 as the boryl radical precursor and PhSH as the… read more here.
Keywords: base boryl; boryl radicals; lewis base; desulfurizative reduction ... See more keywords