Articles with "base complex" as a keyword



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Synthesis and Characterization of Pd Schiff Base Complex Immobilized onto Functionalized Nanoporous MCM-41 and its Catalytic Efficacy in the Suzuki, Heck and Stille Coupling Reactions

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Published in 2017 at "Catalysis Letters"

DOI: 10.1007/s10562-016-1957-5

Abstract: The present work describes the use of palladium-vanillin-Schiff-base complex immobilized on MCM-41 nanostructure as efficient catalyst for the Suzuki–Miyaura, Stille and Mizoroki–Heck reactions of several aryl halides under aerobic conditions. All the reactions were carried… read more here.

Keywords: complex immobilized; suzuki; base complex; catalyst ... See more keywords
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Evaluation of invitro α-amylase and α-glucosidase inhibitory potential of N2O2 schiff base Zn complex

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Published in 2017 at "Arabian Journal of Chemistry"

DOI: 10.1016/j.arabjc.2014.07.002

Abstract: Abstract The evaluation of the antioxidant, antibacterial and enzyme inhibition effects of N 2 O 2 Schiff base Zn complex was investigated. The percentage scavenging activity of hydroxyl radical (IC 50 -0.21 μg), ABTS (IC 50… read more here.

Keywords: complex; base complex; amylase glucosidase; znl complex ... See more keywords
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Regenerable and selective histamine impedimetric sensor based on hydroxyl functionalised Schiff base complex electrode

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Published in 2021 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2021.138186

Abstract: Abstract The presence of histamine in foods due to improper storage of foods is associated with toxicological risk and quality indicators. An impedimetric sensor was developed by immobilising fluoro-substituted hydroxyl functionalised Schiff base zinc(II) complex… read more here.

Keywords: electrode; impedimetric sensor; histamine; base complex ... See more keywords
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A zinc Schiff base complex inhibits cancer progression both in vivo and in vitro by inducing apoptosis.

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Published in 2017 at "Environmental toxicology and pharmacology"

DOI: 10.1016/j.etap.2017.11.004

Abstract: Cancer chemotherapy suffers from selectivity and undesired toxicity of the drugs. Since zinc is a biocompatible tracer element and cysteine derivatives are used in cancer chemoprevention, we intend to develop a complex of zinc and… read more here.

Keywords: zinc schiff; non toxic; zinc; base complex ... See more keywords
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Synthesis and X-ray crystal structure of a Molybdenum(VI) Schiff base complex: Design of a new catalytic system for sustainable olefin epoxidation

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.119775

Abstract: Abstract A targeted new dioxo molybdenum(VI) ONO Schiff base complex was prepared for catalyzing epoxidation of olefins in water. This complex was characterized by FT-IR, NMR, UV–Vis, and X-ray crystallography techniques. DFT calculations are additionally… read more here.

Keywords: base complex; epoxidation; ray; schiff base ... See more keywords
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Synthesis of polymer supported Ni (II)-Schiff Base complex and its usage as a catalyst in sodium borohydride hydrolysis

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Published in 2018 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2018.02.023

Abstract: Abstract Influence of using as catalysis, Ni-Schiff Base complex which we previously synthesized [1] used to support with amberzyme oxirane resin (A.O.R.) polymer for increasing the catalytic activity in NaBH4 hydrolysis reaction, to hydrogen generation… read more here.

Keywords: polymer; base complex; hydrolysis; catalyst ... See more keywords
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Metal-Schiff Base complex catalyst in KBH4 hydrolysis reaction for hydrogen production

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Published in 2019 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2019.01.229

Abstract: Abstract It is the first study to synthesize Co(II)-Schiff Base complex and to use it like a catalyst for potassium borohydride hydrolysis reaction to hydrogen production. Co(II)-complex is synthesized with CoCl2·6H2O and 5-Amino-2,4-dichlorophenol-3,5-di-tert-butylsalisylaldimine ligand. KBH4… read more here.

Keywords: catalyst; reaction; base complex; schiff base ... See more keywords
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Electrocatalytic reduction of nitrite and bromate and their highly sensitive determination on carbon paste electrode modified with new copper Schiff base complex

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Published in 2017 at "Journal of Electroanalytical Chemistry"

DOI: 10.1016/j.jelechem.2017.04.046

Abstract: Abstract A modified carbon paste electrode by Cu II -( N , N ′-bis(2,5-dihydroxybenzylidene)-1,2-diaminoethane) (Cu II -DHB) as a new synthesized copper Schiff base complex. This modified electrode (ME) was constructed for the simultaneous determination… read more here.

Keywords: carbon paste; base complex; electrode; nitrite bromate ... See more keywords
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A new nanohybrid material constructed from Keggin-type polyoxometalate and Cd(II) semicarbazone Schiff base complex with excellent adsorption properties for the removal of cationic dye pollutants

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Published in 2017 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2016.10.081

Abstract: Abstract A novel nanohybrid material containing a Cd(II) semicarbazone Schiff base complex and phosphomolybdic acid, [Cd(H2L+)6][H2L]+4[PMo12O40]4·18CH3OH·4H2O (1), [HL = pyridine-2-carbaldehyde semicarbazone] was prepared by a simple sonochemical route and characterized by 1HNMR, 13CNMR, FT-IR, UV–vis, PXRD, FESEM,… read more here.

Keywords: adsorption; semicarbazone; semicarbazone schiff; nanohybrid material ... See more keywords
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Synthesis and characterization of a Pd(0) Schiff base complex anchored on magnetic nanoporous MCM-41 as a novel and recyclable catalyst for the Suzuki and Heck reactions under green conditions

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Published in 2017 at "Chinese Journal of Catalysis"

DOI: 10.1016/s1872-2067(17)62865-1

Abstract: Abstract A Pd Schiff base complex was immobilized onto the surface of magnetic MCM-41 (Fe3O4@MCM-41@Pd(0)-P2C) as a novel, eco-friendly, and recyclable heterogeneous nanocatalyst and fully characterized by FT-IR, VSM, EDS, transmission electron microscopy, scanning electron… read more here.

Keywords: microscopy; mcm; base complex; suzuki heck ... See more keywords
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Cobalt(II) Pentaaza-Macrocyclic Schiff Base Complex as Catalyst for Light-Driven Hydrogen Evolution in Water: Electrochemical Generation and Theoretical Investigation of the One-Electron Reduced Species.

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Published in 2019 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.9b00447

Abstract: We previously reported that the tetraazamacrocyclic Schiff base complex [CoIII(CR14)(X)2] n+ (CR14 = 2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),2,11,13,15-pentaene, X = Cl ( n = 1) (1-Cl2) or H2O ( n = 3) (1-(H2O)2)) is a very efficient H2-evolving catalyst… read more here.

Keywords: catalyst; electron reduced; base complex; pentaaza macrocyclic ... See more keywords