Kinetics, mechanism and density functional theory calculations on base hydrolysis of α-amino acid esters catalyzed by [Pd(AEMP)(H2O)2]2+ (AEMP = 2-(2-aminoethyl)-1-methylpyrrolidine)
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DOI: 10.1007/s11144-020-01734-7
Abstract: Pd(AEMP)Cl2 (AEMP = 2-(2-aminoethyl)-1-methylpyrrolidine) was synthesized and characterized by spectral and thermal measurements.[Pd(AEMP)(H2O)2]2+ reacts with amino acid esters (L) to form mixed ligand [Pd(AEMP)L]2+ complexes. The kinetics of the base hydrolysis of [Pd(AEMP)L]2+ was studied by a… read more here.
Keywords: base hydrolysis; acid esters; amino acid; hydrolysis ... See more keywords