Proton Conduction in Tröger's Base-Linked Poly(crown ether)s.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b05532
Abstract: Exactly 50 years ago, the ground-breaking discovery of dibenzo[18]crown-6 (DB18C6) by Charles Pedersen led to the use of DB18C6 as a receptor in supramolecular chemistry and a host in host-guest chemistry. We have demonstrated proton… read more here.
Keywords: base linked; ger base; db18c6; chemistry ... See more keywords
Adjustable chiral self-sorting and self-discriminating behaviour between diamond-like Tröger's base-linked cryptands.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03577j
Abstract: Two isomers of Tröger's base-linked cryptands 5a and 5b were synthesized, and both of them have two chiral N-centers, exhibiting rare diamond-like scaffolds. Particularly, when growing from the solution of rac-5a, a single enantiomer RNRN-5a… read more here.
Keywords: linked cryptands; base linked; ger base; chiral self ... See more keywords