Stopping Hydrogen Migration in Its Tracks: The First Successful Synthesis of Group Ten Scorpionate Complexes Based on Azaindole Scaffolds.
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DOI: 10.1021/acs.inorgchem.8b02456
Abstract: The first successful synthesis and characterization of group 10 complexes featuring flexible scorpionate ligands based on 7-azaindole heterocycles are reported herein. Addition of 2 equiv of either K[HB(azaindolyl)3] or Li[HB(Me)(azaindolyl)2] to [M(μ-Cl)(η,1η2-COEOMe)]2 leads to the… read more here.
Keywords: group; hydrogen migration; successful synthesis; based azaindole ... See more keywords