CO 2 to CO: Photo‐ and Electrocatalytic Conversion Based on Re(I) Bis‐Arene Frameworks: Synergisms Between Catalytic Subunits
Sign Up to like & getrecommendations! Published in 2020 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202000147
Abstract: Reduction of CO2 to CO and H2O is a two electron/two proton process. For this process, multinuclear complexes offer advantages by concentrating reduction equivalents more efficiently than mononuclear systems. We present novel complexes with [Re(η6‐C6H6)2]+… read more here.
Keywords: photo electrocatalytic; based bis; conversion based; electrocatalytic conversion ... See more keywords
Synthesis, photophysical and antioxidant properties of carbazole-based bis-thiosemicarbazones
Sign Up to like & getrecommendations! Published in 2019 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-019-03844-x
Abstract: Utilizing Schiff base condensation of the 9-ethylcarbazole-3,6-dicarbaldehyde and thiosemicarbazides, four new N-ethylcarbazole-based bis-thiosemicarbazone compounds 4a–d were successfully synthesized in high yields. The photophysical properties of the targeted compounds 4a–d were investigated using UV–vis absorption and… read more here.
Keywords: synthesis photophysical; based bis; antioxidant properties; properties carbazole ... See more keywords
Polyazomethine and polyphenylene based on 1,2-bis(4-acetylbenzyl)-o-carborane
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DOI: 10.1007/s11172-020-2880-x
Abstract: A model compound, as well as linear and cross-linked polymers polyazomethine and polyphenylene, were synthesized based on 1,2-bis(4-acetylbenzyl)-o-carborane. The thermal stability of polymers was investigated. The structure of polymers was studied by X-ray photoelectron spectroscopy… read more here.
Keywords: based bis; polyazomethine polyphenylene; acetylbenzyl carborane; bis acetylbenzyl ... See more keywords
Synthesis and optical and electrochemical properties of polycyclic aromatic compounds based on bis(benzothiophene)-fused fluorene
Sign Up to like & getrecommendations! Published in 2018 at "Comptes Rendus Chimie"
DOI: 10.1016/j.crci.2018.05.011
Abstract: Abstract Novel polycyclic aromatic compounds (FBTPhO3 and FBTPhO4), which are based on bis(benzothiophene)-fused fluorene functionalized with oligo(ethylene glycol)-substituted phenyl, were synthesized through an intramolecular electrophilic cyclizing reaction. Thermal measurements revealed their excellent thermal stability and… read more here.
Keywords: bis benzothiophene; benzothiophene fused; aromatic compounds; fused fluorene ... See more keywords
Synthesis, structure and catalytic activity of novel five-membered Pd(II) and Pt(II) metallaheterocycles based on 1,2-bis(3,5-dimethylisoxazol-4-yl-methylsulfanyl)ethane
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.07.026
Abstract: Abstract Novel palladium(II) and platinum(II) heterocycles were synthesized based 1,2-bis(3,5-dimethylisoxazol-4-ylmethylsulfanyl)ethane. According to X-ray Crystallographic data in molecule there are two bonds between divalent sulfur atoms and metal atom S-Pd-S to form a five-membered palladacycle in… read more here.
Keywords: dimethylisoxazol; bis dimethylisoxazol; methylsulfanyl ethane; dimethylisoxazol methylsulfanyl ... See more keywords
DNA interaction and anticancer evaluation of new palladium(II), platinum(II) and silver(I) complexes based on (Δ)- and (Λ)-1,2–bis-(1H-benzimidazol-2-yl)-1,2-ethanediol enantiomers
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.020
Abstract: Abstract The synthesis of some new palladium(II), platinum(II) and silver(I) complexes based on (Δ)- and (Λ)-1,2–bis-(1H-benzimidazol-2-yl)-1,2-ethanediol (Δ-H2bie and Λ-H2bie) enantiomers in the absence and presence of the N,N-chelates 2,2′-bipyridyl and 9,10-phenanthroline, and triphenylphosphine is reported.… read more here.
Keywords: platinum silver; silver complexes; palladium platinum; complexes based ... See more keywords
Synthesis and Characterization of Amino-Functional Polyester Dendrimers Based On Bis-MPA with Enhanced Hydrolytic Stability and Inherent Antibacterial Properties
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DOI: 10.1021/acs.biomac.2c01286
Abstract: Polyester dendrimers based on 2,2 bis(hydroxymethyl)propionic acid have been reported to be degradable, non-toxic, and exhibit good antimicrobial activity when decorated with cationic charges. However, these systems exhibit rapid depolymerization, from the outer layer inwards… read more here.
Keywords: chemistry; based bis; bis mpa; dendrimers based ... See more keywords
Nature-Derived Epoxy Resin Monomers with Reduced Sensitizing Capacity—Isosorbide-Based Bis-Epoxides
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DOI: 10.1021/acs.chemrestox.2c00347
Abstract: Epoxy resin systems (ERSs) are a class of thermosetting resins that become thermostable and insoluble polymers upon curing. They are widely used as components of protective surfaces, adhesives, and paints and in the manufacturing of… read more here.
Keywords: dgeba; epoxy resin; based bis; isosorbide based ... See more keywords
Reactivity of a Unique Si(I)–Si(I)-Based η2-Bis(silylene) Iron Complex
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DOI: 10.1021/acs.inorgchem.2c01369
Abstract: In this paper, we report the synthesis of a unique silicon(I)-based metalla-disilirane and report on its reactivity toward TMS-azide and benzophenone. Metal complexes containing disilylenes ((bis)silylenes with a Si–Si bond) are known, but direct ligation… read more here.
Keywords: unique based; iron; reactivity unique; iron complex ... See more keywords
Photosensitization Ability of 1,7-Phenanthroline Based Bis−BODIPYs: Perplexing Role of Intramolecular Rotation on Photophysical Properties
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DOI: 10.1021/acs.jpcc.9b09721
Abstract: 1,7Phenanthroline based bisboron dipyrromethenes (bisBODIPYs) B1 and B2 obtained via small substitutional changes (Cl/SCH3) have been described. The effect of RIR in emission enhancement in a viscous solvent (glycerol) has been studied besides vital role… read more here.
Keywords: phenanthroline based; bis; based bis; bis bodipys ... See more keywords
Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands
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DOI: 10.1039/c9qo00155g
Abstract: [2.2]Paracyclophane-based bis(pyridine) ligands form dinuclear complexes upon coordination to palladium(ii) ions, however, with distinct differences concerning their chiral self-sorting ability. read more here.
Keywords: self sorting; bis pyridine; based bis; chiral self ... See more keywords