A Gd-based borate-carbonate framework exhibiting a large magnetocaloric effect at a low magnetic field.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02624k
Abstract: A 3D borate-carbonate framework, GdB(OH)4CO3 (1), was synthesized. Magnetic study reveals that its MCE is up to 33.5 J kg-1 K-1 at 2 K and 2 T, due to the introduction of a long magnetic… read more here.
Keywords: carbonate framework; based borate; framework exhibiting; borate carbonate ... See more keywords
Chiral BINOL-based borate counterions: from cautionary tale on anion stability to enantioselective Cu-catalyzed cyclopropanation.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05924j
Abstract: The chiral weakly coordinating (3,3'-biphenyl-BINOL)BF2 anion can be generated by the reaction of the BINOL derivative with Cu(NCMe)4BF4. Structural analysis suggest the anion is weakly coordinating to Cu+. However, its use in cyclopropanation reactions leads… read more here.
Keywords: based borate; binol; cyclopropanation; binol based ... See more keywords