Cascade covalent and coordination bond formation for Ti-based cage assembly: catalysis and coordination bifunctionality of TiCl4.
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DOI: 10.1039/c7dt04367h
Abstract: The metallosupramolecular Ti-based M4L4 cage of [Ti4O2L4Cl8] (L = 4-acetamidobenzoic acid) is synthesized via the one-pot solvothermal reaction of 4-aminobenzoic acid, acetic acid and TiCl4. The Ti(iv) ion functions as a Lewis acid catalyst for… read more here.
Keywords: coordination; ticl4; cascade covalent; formation ... See more keywords