Dicyanodistyrylbenzene‐Based Chiral Fluorescence Photoswitches: An Emerging Class of Multifunctional Switches for Dual‐Mode Phototunable Liquid Crystals
Sign Up to like & getrecommendations! Published in 2017 at "Advanced Optical Materials"
DOI: 10.1002/adom.201700014
Abstract: Two novel enantiomeric chiral fluorescence photoswitches containing two chiroptical (S)-(−)- or (R)-(+)-1,1′-bi-2-naphthol covalently bonded to a central dicyanodistyrylbenzene unit are facilely synthesized and efficiently used to construct an optically tunable reflective-photoluminescent cholesteric liquid crystal (LC)… read more here.
Keywords: liquid; based chiral; fluorescence; class ... See more keywords
Recent advances in electrochemical sensors based on chiral and nano-sized imprinted polymers
Sign Up to like & getrecommendations! Published in 2018 at "Current Opinion in Electrochemistry"
DOI: 10.1016/j.coelec.2017.11.018
Abstract: Summary The successful development of analytical tools for the detection of a given target molecule at low concentrations is strongly dependent on the use of high affinity binders. To date, antibodies are widely used as… read more here.
Keywords: electrochemical sensors; based chiral; sensors based; recent advances ... See more keywords
Homobinuclear compounds based on chiral oxazolidine ligand: from solid state study to aqueous solution dynamics
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120664
Abstract: Abstract Two binuclear complexes of molecular formula [CoIICl(H3L)(H2O)]2Cl2 (1) and [CuIICl2(H3L)]2 (2), where H3L stands for the chiral ligand (2-pyridin-2-yl-1,3-oxazolidine-4,4-diyl)dimethanol) were obtained. The complexes and H3L ligand were formed using an one-pot strategy and characterized… read more here.
Keywords: based chiral; h3l; compounds based; spectroscopy ... See more keywords
Liquid chromatographic enantioseparation of carbocyclic &bgr;‐amino acids possessing limonene skeleton on macrocyclic glycopeptide‐based chiral stationary phases
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Pharmaceutical and Biomedical Analysis"
DOI: 10.1016/j.jpba.2017.06.010
Abstract: Graphical abstract Figure. No Caption available. HighlightsEnantiomers of carbocyclic &bgr;‐amino acids possessing limonene skeleton were separated.Macrocyclic glycopeptide‐based chiral stationary phases were thermodynamically characterized.Decreased retentions were accompanied with increased separation factors with increasing temperature. Abstract Polar‐ionic… read more here.
Keywords: based chiral; glycopeptide based; bgr amino; dgr ... See more keywords
Highly Enantioselective Synthesis of Chiral Benzhydrols via Manganese Catalyzed Asymmetric Hydrogenation of Unsymmetrical Benzophenones Using an Imidazole-Based Chiral PNN Tridentate Ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01056
Abstract: A series of Mn(I) catalysts containing imidazole-based chiral PNN tridentate ligands with controllable "side arm" groups have been established, enabling the asymmetrical hydrogenation of unsymmetrical benzophenones with outstanding activity (up to 13 000 TON) and excellent… read more here.
Keywords: chiral pnn; based chiral; pnn tridentate; unsymmetrical benzophenones ... See more keywords
A DNA Origami-Based Chiral Plasmonic Sensing Device.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b19153
Abstract: Accurate and reliable biosensing is crucial for environmental monitoring, food safety, and diagnostics. Spatially reconfigurable DNA origami nanostructures are excellent candidates for the generation of custom sensing probes. Here we present a nanoscale biosensing device… read more here.
Keywords: origami based; based chiral; chiral plasmonic; dna origami ... See more keywords
Graphene-based chiral liquid crystal materials for optical applications
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry C"
DOI: 10.1039/c8tc04947e
Abstract: Synthesis, theory, and applications of graphene-based chiral liquid crystal materials. read more here.
Keywords: chiral liquid; applications graphene; crystal materials; liquid crystal ... See more keywords
Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex
Sign Up to like & getrecommendations! Published in 2020 at "RSC Advances"
DOI: 10.1039/d0ra07271k
Abstract: The facile synthesis of tetrahydroquinoline-based chiral carbene precursors is reported. A rare Au⋯H–C(sp3) interaction between Au(i) and the hydrogen atom was observed in the crystal structure of a related NHC–gold complex. read more here.
Keywords: chiral carbene; tetrahydroquinoline based; syntheses tetrahydroquinoline; based chiral ... See more keywords
First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00114k
Abstract: The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were fully characterized, and the nature… read more here.
Keywords: based chiral; first example; chiral helices; luminescent borasiloxane ... See more keywords
Amino Acid Substituted Polyacetylene Based Chiral Core-Shell Microspheres: Helix Structure Induction and Application for Chiral Resolution and Adsorption
Sign Up to like & getrecommendations! Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d1py01067k
Abstract: The chiral composite materials were synthesized by the helical polymers directly compounded with the substrate at present, due to changes in chemical bonds and steric hindrance during the compounding process... read more here.
Keywords: amino acid; based chiral; chiral core; polyacetylene based ... See more keywords
Binaphthol-based chiral host molecules for efficient solution-processed circularly polarized OLEDs.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06420k
Abstract: Two kinds of chiral hosts, named (R/S)-BN-mCP and (R/S)-BN-2mCP, are prepared. Solution processable circularly polarized organic light-emitting diodes (CP-OLEDs) based on the chiral hosts and achiral emitter Ir(mypp)3 present the maximum external quantum efficiency (EQEmax)… read more here.
Keywords: solution processed; chiral host; circularly polarized; based chiral ... See more keywords