Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201901211
Abstract: As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that… read more here.
Keywords: aziridination catalysts; aziridination; complexes styrene; styrene aziridination ... See more keywords
Medicinal Applications of Gold(I/III)-Based Complexes Bearing N-Heterocyclic Carbene and Phosphine Ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.04.023
Abstract: Abstract Phosphines are the most studied ligands on gold-based metallodrugs, whereas N-heterocyclic carbenes (NHCs) have been emerging in the past years as potential alternative ligands for medicinal applications. Indeed, in both cases, phosphine and NHC… read more here.
Keywords: ligands medicinal; iii; applications gold; phosphine ... See more keywords
Investigation of resonance assisted hydrogen bond (RAHB) in some pyridine-based complexes: Intramolecular and intermolecular interactions
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.127546
Abstract: Abstract Intra- and intermolecular hydrogen bonding interactions in some pyridine-based complexes that have R groups without (H, –C2H5, and –C4H9) and with (−C2H3, –C4H5, –C6H7, and –C8H9) π-conjugated system were investigated using quantum mechanical calculations… read more here.
Keywords: hydrogen; resonance; hydrogen bond; pyridine based ... See more keywords
A Dual-Pronged Approach: A Ruthenium(III) Complex That Modulates Amyloid-β Aggregation and Disrupts Its Formed Aggregates.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01651
Abstract: Alzheimer's disease (AD) is a devastating neurological disorder for which soluble oligomers of the peptide amyloid-β (Aβ) are now recognized as the neurotoxic species. Metal-based therapeutics are uniquely suited to target Aβ, with ruthenium-based (Ru)… read more here.
Keywords: aggregation; based complexes; dual pronged; iii ... See more keywords
Manipulating Solvothermal Coordination-Catalyzed In Situ Tandem Reactions to Construct Dysprosium-Based Complexes with Different Shapes and Zero-Field SMM Behaviors.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03238
Abstract: By changing the coordination anions (OAc- and Cl-), reaction temperature, solvent, and ligand substituents, four Dy(III)-based complexes were obtained by directed synthesis, which are [Dy4(L1)2(L2)2(OAc)4]·4C2H5OH·3H2O (1, L1 = 1,3,4-thiadiazole-2,5-diamine, H4L2 = 6,6'-(((1,3,4-thiadiazole-2,5-diyl)bis(azanediyl))bis(((3-ethoxy-2-hydroxybenzyl)oxy)methylene))bis(2-ethoxyphen), [Dy4(L3)4(OAc)4]·C2H5OH·H2O (2, H3L3… read more here.
Keywords: tandem reactions; based complexes; situ tandem; zero field ... See more keywords
Theoretical Investigation of the Electronic Properties of Three Vanadium Phthalocyaninato (Pc) Based Complexes: PcV, PcVO, and PcVI.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02788
Abstract: The electronic properties of three vanadium phthalocyaninato (Pc) based complexes (PcV, PcVO, and PcVI; I-III, respectively) were theoretically investigated and corresponding VL2,3-edge XAS spectra modeled. Ground state (GS) DFT outcomes indicated that II is more… read more here.
Keywords: properties three; phthalocyaninato based; three vanadium; vanadium phthalocyaninato ... See more keywords
Chromium-Based Complexes Bearing Aminophosphine and Phosphine–Imine–Pyrryl Ligands for Selective Ethylene Tri/Tetramerization
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c02083
Abstract: A series of Cr-based complexes 6–10 bearing aminophosphine (P,N) ligands Ph2P–L–NH2 [L = CH2CH2 (1), L = CH2CH2CH2 (2), and L = C6H4CH2 (3)] and phosphine–imine–pyrryl (P,N,N) ligands 2-(Ph2P–L–N=CH)C4H3NH [L = CH2CH2CH2 (4) and L… read more here.
Keywords: ethylene tri; complexes bearing; tri tetramerization; based complexes ... See more keywords
Symmetry correlations between crystallographic and photoluminescence study of ternary β-diketone europium(iii) based complexes using 1,10-phenanthroline as the ancillary ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02580d
Abstract: This work entails deep red emitting EuIII based complexes with a variety of ternary β-diketonate ligands and 1,10-phenanthroline as the ancillary ligand in the system. The solid state structure and spectroscopic analysis has been outlaid… read more here.
Keywords: europium; phenanthroline ancillary; photoluminescence; europium iii ... See more keywords
Heterogenisation of polyoxometalates and other metal-based complexes in metal-organic frameworks: from synthesis to characterisation and applications in catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Society reviews"
DOI: 10.1039/d0cs00323a
Abstract: The last few years have seen huge growing interest in the heterogenisation of molecular catalysts since it allows combining the advantages of homogeneous and heterogeneous catalyses. Besides bringing recyclability, the immobilisation of the catalyst may… read more here.
Keywords: metal organic; heterogenisation polyoxometalates; organic frameworks; based complexes ... See more keywords
Pyridylarsine-based Cu(I) complexes showing TADF mixed with fast phosphorescence: a speeding-up emission rate using arsine ligands.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt03759e
Abstract: Can arsine ligands be preferred over similar phosphines to design Cu(I)-based TADF materials? The present study reveals that arsines can indeed be superior to reach shorter decay times of Cu(I) emitters. This has been exemplified… read more here.
Keywords: emission; rate; arsine ligands; tadf ... See more keywords
Structural and morphological changes of breast cancer cells induced by iron(II) complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr08301e
Abstract: Metal-based complexes are well-established cancer chemotherapeutic drug candidates. Although our knowledge regarding their exact activity vs. toxicity profile is incomplete, changes in cell membrane biophysical properties and cytoskeletal structures have been implicated as part of… read more here.
Keywords: iron; microscopy; based complexes; structural morphological ... See more keywords