AIMS simulation study of ultrafast electronically nonadiabatic chemistry of methyl azide and UV-VIS spectroscopic study of azido-based energetic plasticizer bis(1,3-diazido prop-2-yl)malonate
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DOI: 10.1016/j.chemphys.2017.07.008
Abstract: Abstract To gain insight into the ultrafast electronically nonadiabatic chemistry of azido-based energetic plasticizer, we have explored the nonadiabatic chemical dynamics of an azido-based model analog molecule, methyl azide (MAz), using ab initio multiple spawning… read more here.
Keywords: electronically nonadiabatic; based energetic; chemistry; study ... See more keywords
One-step, safe and efficient preparation strategy of nitrate glycerol ether cellulose-based energetic composites with application potential in propellants
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DOI: 10.1016/j.coco.2021.100956
Abstract: Abstract Lately, nitrate glycerol ether cellulose (NGEC), a novel thermoplastic cellulose-based energetic binder, exhibits potential application to replace conventional nitrocellulose (NC) which was commonly used in propellants. This study employs NGEC as insensitive and reinforce… read more here.
Keywords: ether cellulose; glycerol ether; based energetic; cellulose based ... See more keywords
Photochemical Strategies Enable the Synthesis of Tunable Azetidine-Based Energetic Materials.
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DOI: 10.1021/jacs.2c08191
Abstract: Despite their favorable properties, azetidines are often overlooked as lead compounds across multiple industries. This is often attributed to the challenging synthesis of densely functionalized azetidines in an efficient manner. In this work, we report… read more here.
Keywords: azetidine based; based energetic; synthesis; photochemical strategies ... See more keywords
CL-20 based energetic thin films: Micro-spray molding and micro-detonation
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DOI: 10.1063/5.0049075
Abstract: In order to solve the problem of low sample forming efficiency and uncontrollable crystal type in inkjet printing, a formula of explosive ink suitable for micro-spraying is designed by using hexanitrohexaazaisowurtzitane (CL-20) as the main… read more here.
Keywords: thin films; energetic thin; based energetic; detonation ... See more keywords
New 5-Aminotetrazole-Based Energetic Polymers: Synthesis, Structure and Properties
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DOI: 10.3390/ma15196936
Abstract: An N-glycidyl-5-aminotetrazole homopolymer was synthesized herein by nucleophilic substitution of 5-aminotetrazole heterocycles for chlorine atoms in poly-(epichlorohydrin)-butanediol. Copolymers of N-glycidyl-5-aminotetrazole and glycidyl azide with a varied ratio of energetic elements were synthesized by simultaneously reacting… read more here.
Keywords: energetic polymers; synthesis structure; based energetic; polymers synthesis ... See more keywords