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Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00346
Abstract: The P–H functionalized FLPs R(H)PC(AlBis2)═C(H)-CMe3 (1a, R = Bis; 1b, R = Mes; Bis = CH(SiMe3)2) combine the typical FLP properties based on Lewis acidic Al and basic P atoms with the reactivity of a…
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Keywords:
based frustrated;
pairs dipolar;
lewis pairs;
hydrophosphination ... See more keywords
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Published in 2017 at "Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences"
DOI: 10.1098/rsta.2017.0011
Abstract: Reaction of Mes2P─C≡C─Ph (Mes = mesityl) with dineopentylaluminium hydride afforded by hydroalumination a geminal Al/P-based frustrated Lewis pair (FLP; 4). Its steric shielding is relatively low, and its reactivity in various secondary reactions is less hindered by…
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Keywords:
lewis pair;
structure reactivity;
based frustrated;
frustrated lewis ... See more keywords