Articles with "based ligand" as a keyword



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Anthraquinone-based Ligand as MNase Inhibitor: Insights from Inhibition Studies and Generation of a Payload Nanocarrier for Potential Anti-MRSA Therapy.

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Published in 2023 at "ChemMedChem"

DOI: 10.1002/cmdc.202200711

Abstract: The present study highlights the prospect of an anthraquinone-based ligand (C1) as an inhibitor of micrococcal nuclease (MNase) enzyme secreted by Staphylococcus aureus. MNase inhibition rendered by 5.0 µM C1 was ~96% and the ligand… read more here.

Keywords: inhibition; mnase; based ligand; anthraquinone based ... See more keywords
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Experimental and theoretical insights into spectroscopy and electrochemistry of Re(I) carbonyl with oxazoline-based ligand

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.06.047

Abstract: Abstract Structural, spectroscopic and electrochemical properties of a novel rhenium(I) carbonyl complex with oxazoline-based ligand, 2-(4,5-dihydro-2-oxazolyl)quinoline (quinox), are discussed herein. The molecular formula of the title compound fac–[ReCl(CO)3(quinox)] was determined by X-ray analysis and confirmed… read more here.

Keywords: electrochemistry; spectroscopy; based ligand; oxazoline based ... See more keywords
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Oxidovanadium (V and IV) complexes incorporating coumarin based O^N^O ligand: Synthesis, structure and catalytic activities

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Published in 2020 at "Polyhedron"

DOI: 10.1016/j.poly.2019.114241

Abstract: Abstract The tridentate ligand H2L1, [(E)-7-Hydroxy-8-[(2-hydroxy-phenylimino)-methyl]-4-methyl-chromen-2-one] has been used in the present work towards the synthesis of mononuclear oxidovanadium complexes. Three mononuclear complexes [VOL1(OMe)(MeOH)], 1; [VO(L1)(8-Hq)], 2 and [VO(L1)(1,10-phen)], 3 have been successfully synthesized with… read more here.

Keywords: coumarin based; oxidovanadium complexes; complexes incorporating; incorporating coumarin ... See more keywords
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Fabrication of metal coordination-synergistic magnetic imprinted microspheres based on ligand-free Fe3O4-Cu for specific recognition of bovine hemoglobin.

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Published in 2021 at "Talanta"

DOI: 10.1016/j.talanta.2021.122496

Abstract: In this work, a synergistic imprinting strategy combined with metal coordination based on ligand-free Fe3O4-Cu was proposed to fabricate molecularly imprinted polymers (MIPs) for the recognition and isolation of bovine hemoglobin (BHb) specifically in biological… read more here.

Keywords: adsorption; ligand free; metal; based ligand ... See more keywords
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An Anionic Indium-Organic Framework with Spirobifluorene-Based Ligand for Selective Adsorption of Organic Dyes.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.0c02962

Abstract: Ionic metal-organic frameworks (MOFs) with an ionic skeleton and unique porous structures could selectively adsorb charged dyes with specific dimensions. However, the ion-exchange-based and size-exclusion-based process as a chromatography method needs to be further explored.… read more here.

Keywords: adsorption; organic dyes; selective adsorption; spirobifluorene based ... See more keywords
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Nitric Oxide Reactivity of a Cu(II) Complex of an Imidazole-Based Ligand: Aromatic C-Nitrosation Followed by the Formation of N-Nitrosohydroxylaminato Complex.

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Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.7b00069

Abstract: A binuclear Cu(II) complex, 1, [Cu2(L-)2(OAc)](OAc) of imidazole-based ligand LH {LH = 2-(bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methyl)phenol} was synthesized and characterized spectroscopically and structurally. Addition of an equivalent amount of nitric oxide (NO) by a gastight syringe to the… read more here.

Keywords: methyl; nitrosohydroxylaminato complex; based ligand; nitric oxide ... See more keywords
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Spacer Matters: All-Peptide-Based Ligand for Promoting Interfacial Proteolysis and Plasmonic Coupling.

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Published in 2022 at "Nano letters"

DOI: 10.1021/acs.nanolett.2c03052

Abstract: Plasmonic coupling via nanoparticle assembly is a popular signal-generation method in bioanalytical sensors. Here, we customized an all-peptide-based ligand that carries an anchoring group, polyproline spacer, biomolecular recognition, and zwitterionic domains for functionalizing gold nanoparticles… read more here.

Keywords: peptide based; plasmonic coupling; ligand; spacer ... See more keywords
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Tetrazine-Based Ligand Transformation Driving Metal–Metal Bond and Mixed-Valence HgI/HgII

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Published in 2018 at "ACS Omega"

DOI: 10.1021/acsomega.8b01861

Abstract: Understanding the self-assembly of cluster aggregates remains an important challenge in coordination chemistry. A chelating tetrazine-based ligand was employed to isolate an unprecedented tetranuclear Hg4 complex exhibiting HgI/HgII mixed valence, which also contains metal–metal bonds.… read more here.

Keywords: tetrazine based; metal; based ligand; mixed valence ... See more keywords
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A new heptadentate picolinate-based ligand and its corresponding Gd(iii) complex: the effect of pendant picolinate versus acetate on complex properties.

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Published in 2017 at "Dalton transactions"

DOI: 10.1039/c7dt04150k

Abstract: To attain high relaxivity as well as stability, a new water-soluble, water-coordinated Gd(iii) complex, which was synthesised by reacting equimolar amounts of picolinate-based ligand H4peada and GdCl3·xH2O at pH ∼ 6.5, was examined. The number… read more here.

Keywords: picolinate; complex; picolinate based; based ligand ... See more keywords
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Hydrogen peroxide assisted photorelease of an anthraquinone-based ligand from [Ru(2,2'-bipyridine)2(9,10-dioxo-9,10-dihydroanthracen-1-olate)]Cl in aqueous solution.

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Published in 2020 at "Dalton transactions"

DOI: 10.1039/d0dt02339f

Abstract: A new class of light-activated ruthenium(ii) complex was designed as a potential blocker of biological functioning, especially for targeting redox reactions within mitochondria under light activation. Based on our concepts the complex [Ru(bipy)2(1-hydroxyanthra-9,10 quinone)]Cl (RU1)… read more here.

Keywords: photorelease anthraquinone; hydrogen peroxide; assisted photorelease; based ligand ... See more keywords
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Robust dicopper(i) μ-boryl complexes supported by a dinucleating naphthyridine-based ligand

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc00848c

Abstract: Copper boryl species have been widely invoked as reactive intermediates in Cu-catalysed C–H borylation reactions, but their isolation and study have been challenging. Use of the robust dinucleating ligand DPFN (2,7-bis(fluoro-di(2-pyridyl)methyl)-1,8-naphthyridine) allowed for the isolation… read more here.

Keywords: boryl; dicopper boryl; boryl complexes; naphthyridine based ... See more keywords