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Published in 2023 at "ChemMedChem"
DOI: 10.1002/cmdc.202200711
Abstract: The present study highlights the prospect of an anthraquinone-based ligand (C1) as an inhibitor of micrococcal nuclease (MNase) enzyme secreted by Staphylococcus aureus. MNase inhibition rendered by 5.0 µM C1 was ~96% and the ligand…
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Keywords:
inhibition;
mnase;
based ligand;
anthraquinone based ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.06.047
Abstract: Abstract Structural, spectroscopic and electrochemical properties of a novel rhenium(I) carbonyl complex with oxazoline-based ligand, 2-(4,5-dihydro-2-oxazolyl)quinoline (quinox), are discussed herein. The molecular formula of the title compound fac–[ReCl(CO)3(quinox)] was determined by X-ray analysis and confirmed…
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Keywords:
electrochemistry;
spectroscopy;
based ligand;
oxazoline based ... See more keywords
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Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114241
Abstract: Abstract The tridentate ligand H2L1, [(E)-7-Hydroxy-8-[(2-hydroxy-phenylimino)-methyl]-4-methyl-chromen-2-one] has been used in the present work towards the synthesis of mononuclear oxidovanadium complexes. Three mononuclear complexes [VOL1(OMe)(MeOH)], 1; [VO(L1)(8-Hq)], 2 and [VO(L1)(1,10-phen)], 3 have been successfully synthesized with…
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Keywords:
coumarin based;
oxidovanadium complexes;
complexes incorporating;
incorporating coumarin ... See more keywords
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Published in 2021 at "Talanta"
DOI: 10.1016/j.talanta.2021.122496
Abstract: In this work, a synergistic imprinting strategy combined with metal coordination based on ligand-free Fe3O4-Cu was proposed to fabricate molecularly imprinted polymers (MIPs) for the recognition and isolation of bovine hemoglobin (BHb) specifically in biological…
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Keywords:
adsorption;
ligand free;
metal;
based ligand ... See more keywords
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Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02962
Abstract: Ionic metal-organic frameworks (MOFs) with an ionic skeleton and unique porous structures could selectively adsorb charged dyes with specific dimensions. However, the ion-exchange-based and size-exclusion-based process as a chromatography method needs to be further explored.…
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Keywords:
adsorption;
organic dyes;
selective adsorption;
spirobifluorene based ... See more keywords
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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00069
Abstract: A binuclear Cu(II) complex, 1, [Cu2(L-)2(OAc)](OAc) of imidazole-based ligand LH {LH = 2-(bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methyl)phenol} was synthesized and characterized spectroscopically and structurally. Addition of an equivalent amount of nitric oxide (NO) by a gastight syringe to the…
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Keywords:
methyl;
nitrosohydroxylaminato complex;
based ligand;
nitric oxide ... See more keywords
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Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.2c03052
Abstract: Plasmonic coupling via nanoparticle assembly is a popular signal-generation method in bioanalytical sensors. Here, we customized an all-peptide-based ligand that carries an anchoring group, polyproline spacer, biomolecular recognition, and zwitterionic domains for functionalizing gold nanoparticles…
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Keywords:
peptide based;
plasmonic coupling;
ligand;
spacer ... See more keywords
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Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01861
Abstract: Understanding the self-assembly of cluster aggregates remains an important challenge in coordination chemistry. A chelating tetrazine-based ligand was employed to isolate an unprecedented tetranuclear Hg4 complex exhibiting HgI/HgII mixed valence, which also contains metal–metal bonds.…
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Keywords:
tetrazine based;
metal;
based ligand;
mixed valence ... See more keywords
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Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt04150k
Abstract: To attain high relaxivity as well as stability, a new water-soluble, water-coordinated Gd(iii) complex, which was synthesised by reacting equimolar amounts of picolinate-based ligand H4peada and GdCl3·xH2O at pH ∼ 6.5, was examined. The number…
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Keywords:
picolinate;
complex;
picolinate based;
based ligand ... See more keywords
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Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02339f
Abstract: A new class of light-activated ruthenium(ii) complex was designed as a potential blocker of biological functioning, especially for targeting redox reactions within mitochondria under light activation. Based on our concepts the complex [Ru(bipy)2(1-hydroxyanthra-9,10 quinone)]Cl (RU1)…
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Keywords:
photorelease anthraquinone;
hydrogen peroxide;
assisted photorelease;
based ligand ... See more keywords
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1
Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc00848c
Abstract: Copper boryl species have been widely invoked as reactive intermediates in Cu-catalysed C–H borylation reactions, but their isolation and study have been challenging. Use of the robust dinucleating ligand DPFN (2,7-bis(fluoro-di(2-pyridyl)methyl)-1,8-naphthyridine) allowed for the isolation…
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Keywords:
boryl;
dicopper boryl;
boryl complexes;
naphthyridine based ... See more keywords