Thiophene‐Based Ligands: Design, Synthesis and Their Utilization for Optical Assignment of Polymorphic‐Disease‐Associated Protein Aggregates
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DOI: 10.1002/cbic.202300044
Abstract: The development of ligands for detecting protein aggregates is of great interest, as these aggregated proteinaceous species are the pathological hallmarks of several devastating diseases, including Alzheimer's disease. In this regard, thiophene‐based ligands have emerged… read more here.
Keywords: disease; based ligands; thiophene based; protein aggregates ... See more keywords
Pyrrolidine‐Based P,O Ligands from Carbohydrates: Easily Accessible and Modular Ligands for the Ir‐Catalyzed Asymmetric Hydrogenation of Minimally Functionalized Olefins
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DOI: 10.1002/cctc.201801485
Abstract: The potential of P,O‐iminosugar based ligands in the Ir‐catalyzed asymmetric hydrogenation of minimally functionalized olefins is presented. These new ligands were prepared from easily available carbohydrates (D‐mannose, D‐ribose and D‐arabinose). The stereochemical and polyfunctional diversity… read more here.
Keywords: catalyzed asymmetric; hydrogenation; based ligands; asymmetric hydrogenation ... See more keywords
Bidentate N‐based Ligands for Highly Reusable, Ligand‐coordinated, Supported Pt Hydrosilylation Catalysts
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DOI: 10.1002/cctc.202000085
Abstract: A significant challenge in designing supported metal‐ligand catalysts for solution‐phase reactions is the stabilization of the metal active sites against leaching into solution. Here, we examine alkene hydrosilylation reactions as model systems to improve the… read more here.
Keywords: ligand coordinated; based ligands; metal; bidentate based ... See more keywords
Protein A-based ligands for affinity chromatography of antibodies
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DOI: 10.1016/j.cjche.2020.12.001
Abstract: Abstract Protein A chromatography is a key technology in the industrial production of antibodies, and a variety of commercial protein A adsorbents are available in shelf. High stability and binding capacity of a protein A… read more here.
Keywords: protein; chromatography; binding capacity; protein based ... See more keywords
Indazole-based ligands for estrogen-related receptor α as potential anti-diabetic agents.
Sign Up to like & getrecommendations! Published in 2017 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2017.07.015
Abstract: Estrogen-related receptor α (ERRα) is an orphan nuclear receptor that has been functionally implicated in the regulation of energy homeostasis. Herein is described the development of indazole-based N-alkylthiazolidenediones, which function in biochemical assays as selective… read more here.
Keywords: indazole based; based ligands; ligands estrogen; receptor ... See more keywords
Platinum(II) and palladium(II) complexes of tridentate hydrazone-based ligands as selective guanine quadruplex binders.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.003
Abstract: Several tridentate hydrazone-based ligands, synthesized by a condensation reaction of either 2-(1-methylhydrazinyl)pyridine or 2-(1-methylhydrazinyl)quinoline with an aldehyde (picolinaldehyde, 1H-pyrrole-2-carbaldehyde, 2-mercaptobenzaldehyde, 2-aminobenzaldehyde) have been reacted with palladium(II) and platinum(II) salts and precursor complexes to yield nine… read more here.
Keywords: hydrazone based; based ligands; guanine quadruplex; spectroscopy ... See more keywords
Influence of pyridine-based ligands on photostability of MAPbI3 thin films
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DOI: 10.1016/j.mencom.2021.04.013
Abstract: The effect of pyridine-based ligands, capable of coordinating e improving stability with Pb2+ defect sites through nitrogen atoms, on the photostability of MAPbI3 thin films under solar radiation of 70–80 mW cm−2 at 50–60 °C in an inert… read more here.
Keywords: based ligands; photostability mapbi3; mapbi3 thin; pyridine based ... See more keywords
Plasmon-Induced Photoreaction of o-Nitrobenzyl-Based Ligands under 550 nm Light
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b00707
Abstract: We have studied the plasmon-driven photoreaction of a dual thiol-anchored o-nitrobenzyl-based photouncaging ligand on silver nanoparticles. Previous results have shown that this compound strongly anchors to gold surfaces, and a 1 J/cm2 dose of UV… read more here.
Keywords: photoreaction; based ligands; photoreaction nitrobenzyl; induced photoreaction ... See more keywords
Displacement of carbonates in Ca2UO2(CO3)3 by amidoxime-based ligands from free-energy simulations.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt03412a
Abstract: Amidoxime-based ligands are effective in uranium extraction by displacing carbonates in Ca2UO2(CO3)3, the dominant uranyl species in seawater. However, a detailed understanding of the displacement process has been lacking. Here we use classical molecular dynamics… read more here.
Keywords: based ligands; amidoxime based; ca2uo2 co3; free energy ... See more keywords
DO2A-based ligands for gallium-68 chelation: synthesis, radiochemistry and ex vivo cardiac uptake.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02354b
Abstract: Radiolabelled lipophilic cations could potentially be used to non-invasively image mitochondrial dysfunction in cardiovascular disease, building on their current role as perfusion imaging agents. We have synthesised and radiolabelled two series of DO2A-based radiotracers, with… read more here.
Keywords: uptake; based ligands; gallium chelation; do2a based ... See more keywords
M-CPOnes: transition metal complexes with cyclopropenone-based ligands for light-triggered carbon monoxide release.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00835a
Abstract: A new class of CO-releasing molecules, M-CPOnes, was prepared combining cyclopropenone-based ligands for CO release with the modular scaffold of transition metal complexes. In proof-of-concept studies, M-CPOnes based on ZnII, FeII and CoII are stable… read more here.
Keywords: spectroscopy; based ligands; cyclopropenone; release ... See more keywords