Electronic insights into aminoquinoline-based PNHN ligands: protonation state dictates geometry while coordination environment dictates N-H acidity and bond strength.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01556k
Abstract: A variety of transition metal complexes bearing aminoquinoline PNHH'-R ligands R = Ph (L1H), Cy (L2H) and their amido analogues are reported for rhodium(I) ([Rh(L1H)(PPh3)]+1 and Rh(L1)(PPh3) 2), cobalt(II) (Co(L2)(Cl) 3), and iron(II) ([Fe(L1H)2]2+5, Fe(L1)26,… read more here.
Keywords: insights aminoquinoline; based pnhn; geometry; electronic insights ... See more keywords