2D Windmill-like Ln-Containing Organophosphonate-Based Polyoxomolybdates: Synthesis, Characterization, Fluorescence, and Magnetism.
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DOI: 10.1021/acs.inorgchem.2c01618
Abstract: By integration of {Ln(H2O)6}3+ into organophosphonate-based polyoxometalates, three Ln-containing organophosphonate-functionalized polyoxomolybdates Na1.5H1.5[{Ln(H2O)6}2{(Mo3O8)(O3PC(C3H6NH3)OPO3)}4]·(CH3CO2)·43H2O (Ln = Eu (1), Tb (2), and Dy (3)) are successfully prepared and systematically characterized. The X-ray crystallography analyses display complexes 1-3 crystallize… read more here.
Keywords: organophosphonate based; windmill like; organophosphonate; based polyoxomolybdates ... See more keywords