Articles with "based redox" as a keyword



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Octahedral-based redox molecular sieve M-PKU-1: Isomorphous metal-substitution, catalytic oxidation of sec-alcohol and related catalytic mechanism

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Published in 2017 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2017.05.007

Abstract: Abstract Octahedral-based redox molecular sieves M-PKU-1 (M Cr, Fe) were synthesized by isomorphous metal-substitution and used as catalysts for catalytic dehydrogenation of sec-alcohols using H2O2 as oxidant. Various characterizations, such as X-ray diffraction Rietveld refinement… read more here.

Keywords: based redox; octahedral based; isomorphous metal; metal substitution ... See more keywords
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Chondroitin sulfate-based redox-responsive nanoparticles for melanoma-targeted drug delivery

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Published in 2020 at "Journal of Drug Delivery Science and Technology"

DOI: 10.1016/j.jddst.2020.102033

Abstract: Abstract The therapeutic efficacy of most chemotherapeutic drugs is hampered by low water solubility, poor stability, serious side effects, and lack of tumor selectivity. To solve these issues, chondroitin sulfate (CS)-based redox-responsive nanoparticles were developed.… read more here.

Keywords: redox responsive; based redox; responsive nanoparticles; sulfate based ... See more keywords
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Experimental Approaches for Investigating Disulfide-Based Redox Relays in Cells.

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Published in 2022 at "Chemical research in toxicology"

DOI: 10.1021/acs.chemrestox.2c00123

Abstract: Reversible oxidation of cysteine residues within proteins occurs naturally during normal cellular homeostasis and can increase during oxidative stress. Cysteine oxidation often leads to the formation of disulfide bonds, which can impact protein folding, stability,… read more here.

Keywords: protein folding; redox relays; thiol dependent; based redox ... See more keywords
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Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence.

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Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.0c03244

Abstract: Metal ligand cooperativity is a powerful strategy in transition metal chemistry. This type of mechanism for the activation of O2 is best exemplified by heme centers in biological systems. While aerobic oxidations with Fe and… read more here.

Keywords: ligand based; based redox; chemistry; superoxo complex ... See more keywords
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Utilization of BODIPY-based redox events to manipulate the Lewis acidity of fluorescent boranes.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d1cc06400b

Abstract: This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a borane. The redox-active nature of the BODIPY dye is utilized to generate a family of molecular boranes that are… read more here.

Keywords: bodipy based; events manipulate; based redox; utilization bodipy ... See more keywords
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A phosphine-based redox method for direct conjugation of disulfides.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc04967h

Abstract: Technologies for cysteine disulfide detection and conjugation are pivotal to understanding protein functions and developing disulfide-derived therapeutic agents. Currently, disulfide modification requires reductive cleavage prior to functionalization, posing challenges to differentiating disulfides from free thiols.… read more here.

Keywords: based redox; direct conjugation; method; conjugation ... See more keywords
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Thiolā€based redox sensing in the methyltransferase associated sensor kinase RdmS in Methanosarcina acetivorans

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Published in 2019 at "Environmental Microbiology"

DOI: 10.1111/1462-2920.14541

Abstract: Organisms have evolved signal transduction systems to quickly adapt their lifestyle to internal and environmental changes. While protein kinases and two-component systems are widely distributed in Bacteria, they are also found in Archaea but are… read more here.

Keywords: kinase rdms; methanosarcina acetivorans; based redox; kinase ... See more keywords
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Towards Initial Indications for a Thiol-Based Redox Control of Arabidopsis 5-Aminolevulinic Acid Dehydratase

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Published in 2018 at "Antioxidants"

DOI: 10.3390/antiox7110152

Abstract: Thiol-based redox control is one of the important posttranslational mechanisms of the tetrapyrrole biosynthesis pathway. Many enzymes of the pathway have been shown to interact with thioredoxin (TRX) and Nicotinamide adenine dinucleotide phosphate (NADPH)-dependent thioredoxin… read more here.

Keywords: based redox; aminolevulinic acid; thiol based; acid dehydratase ... See more keywords
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Mass Spectrometry-Based Redox and Protein Profiling of Failing Human Hearts

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Published in 2021 at "International Journal of Molecular Sciences"

DOI: 10.3390/ijms22041787

Abstract: Oxidative stress contributes to detrimental functional decline of the myocardium, leading to the impairment of the antioxidative defense, dysregulation of redox signaling, and protein damage. In order to precisely dissect the changes of the myocardial… read more here.

Keywords: human hearts; based redox; mass spectrometry; failing human ... See more keywords