Coordination Affinity of Cu(II)-Based Silsesquioxanes toward N,N-Ligands and Associated Skeletal Rearrangements: Cage and Ionic Products Exhibiting a High Catalytic Activity in Oxidation Reactions.
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DOI: 10.1021/acs.inorgchem.9b03680
Abstract: An unusual skeletal rearrangement of piperazine into ethylenediamine has been observed for the first time as a result of an attempt to synthesize a piperazine-linked metal-organic framework (MOF) using cage Cu(II),Na-phenylsilsequixane as a potential building… read more here.
Keywords: based silsesquioxanes; ionic products; oxidation; coordination affinity ... See more keywords