Molecular-Engineered Biradicals Based on the YIII-Phthalocyanine Platform.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c11760
Abstract: A mixed-ligand phthalocyanine/porphyrin yttrium(III) radical double-decker complex (DD) was synthesized using the custom-made 5,10,15-tris(4-methoxyphenyl)-20-(4-((trimethylsilyl)ethynyl)phenyl)porphyrin. The trimethylsilyl functionality was then used to couple two such complexes into biradicals through rigid tethers. Glaser coupling was used to… read more here.
Keywords: engineered biradicals; based yiii; phthalocyanine platform; yiii phthalocyanine ... See more keywords