A Study of Kamlet–Taft β and π* Scales of Solvent Basicity and Polarity/Polarizability Using Computationally Derived Molecular Properties
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solution Chemistry"
DOI: 10.1007/s10953-020-00979-z
Abstract: The Kamlet and Taft solvent basicity parameter, β, and solvent polarity/polarizability parameter, π*, were analyzed in terms of properties of the solvent molecules derived from computational chemistry. The analysis of β, using a larger data… read more here.
Keywords: chemistry; basicity; polarizability; polarity polarizability ... See more keywords
Structure Evolution of Slag Films of Ultrahigh-Basicity Mold Flux During Solidification
Sign Up to like & getrecommendations! Published in 2017 at "Metallurgical and Materials Transactions B"
DOI: 10.1007/s11663-017-1004-y
Abstract: A higher-basicity mold flux (binary basicity 1.74) for peritectic grades showed similar solidification behavior to conventional high-basicity fluxes. Upon solidification of the mold flux onto a water-cooled copper probe, interfacial roughness at the copper-mold flux… read more here.
Keywords: basicity mold; basicity; mold flux; solidification ... See more keywords
Impact of Sinter Basicity and Alumina on Softening Melting Behavior in Blast Furnace
Sign Up to like & getrecommendations! Published in 2019 at "Transactions of the Indian Institute of Metals"
DOI: 10.1007/s12666-019-01848-0
Abstract: Softening–melting (SM) experiments have been carried out by using sinter basicity (CaO/SiO 2 ) 1.74 to 2.09 and alumina content 2.90 to 3.39%. The objective of the work is to find the relation between sinter… read more here.
Keywords: temperature; sinter basicity; furnace; basicity alumina ... See more keywords
SYNTHESIS AND CHARACTERIZATION OF HYDROCALUMITE: INFLUENCE OF AGING CONDITIONS ON THE STRUCTURE, TEXTURAL PROPERTIES, THERMAL STABILITY, AND BASICITY
Sign Up to like & getrecommendations! Published in 2020 at "Clays and Clay Minerals"
DOI: 10.1007/s42860-019-00049-6
Abstract: Hydrocalumite (HC) is a type of synthetic layered double hydroxide (LDH) that has many important industrial uses and is commonly synthesized by a co-precipitation method in a water:ethanol (2:3) mixture; however, atmospheric carbon dioxide interferes… read more here.
Keywords: temperature; properties thermal; textural properties; basicity ... See more keywords
Effect of Lewis basicity on the continuous gas phase condensation of benzaldehyde with acetophenone over MgO
Sign Up to like & getrecommendations! Published in 2021 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2021.118277
Abstract: Abstract We have investigated the effect of Lewis basicity in the continuous gas phase condensation of acetophenone + benzaldehyde over MgO. The catalysts were prepared by ammonia precipitation, hydration and calcination to generate MgO with… read more here.
Keywords: mgo; effect lewis; continuous gas; lewis basicity ... See more keywords
Highly dispersed Ni/NiCaAlOx nanocatalyst derived from ternary layered double hydroxides for phenol hydrogenation: Spatial confinement effects and basicity of the support
Sign Up to like & getrecommendations! Published in 2021 at "Applied Clay Science"
DOI: 10.1016/j.clay.2021.106003
Abstract: Abstract Mixed metal oxides derived from layered double hydroxides (LDHs) present favorable characteristics, mainly linked to the homogeneous distribution of the Ni species inside the lattice of metal oxides, resulting in ultrafine Ni(0) nanocatalysts. Herein,… read more here.
Keywords: confinement effects; basicity; spatial confinement; support ... See more keywords
Toward tailoring of robust organobases based on extended π-systems: A density functional theory study of the carbonyl basicity
Sign Up to like & getrecommendations! Published in 2020 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2019.112700
Abstract: Abstract The gas phase proton affinity (PA) and basicity (GB) of a series of extended π-systems, possessing carbonyl as the most basic sites, were calculated using the DFT-B3LYP theoretical method. The backbone of the polycyclic… read more here.
Keywords: organobases based; tailoring robust; extended systems; toward tailoring ... See more keywords
Modulating hydrogen-bond basicity within the context of protein-ligand binding: A case study with thrombin inhibitors that reveals a dominating role for desolvation.
Sign Up to like & getrecommendations! Published in 2017 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2016.09.038
Abstract: Understanding subtle aspects of hydrogen bonding is a challenging but crucial task to improve our ability to design ligands with high affinity for protein hosts. To gain a deeper understanding of these aspects, we investigated… read more here.
Keywords: desolvation; affinity; basicity; ligand ... See more keywords
Tailoring and exploring the basicity of magnesium oxide nanostructures in ionic liquids for Claisen-Schmidt condensation reaction
Sign Up to like & getrecommendations! Published in 2018 at "Energy"
DOI: 10.1016/j.energy.2018.07.036
Abstract: Abstract Solid basic catalysts are extremely useful for green catalytic processes because of their high activity, easy separation, and minimal corrosion. Herein, we report the development and effect of the basicity of five various MgO… read more here.
Keywords: mgo nanostructures; effect; reaction; basicity ... See more keywords
Optical basicity and electronic polarizability of zinc borotellurite glass doped La3+ ions
Sign Up to like & getrecommendations! Published in 2017 at "Results in physics"
DOI: 10.1016/j.rinp.2017.01.014
Abstract: Zinc borotellurite glasses doped with lanthanum oxide were successfully prepared through melt-quenching technique. The amorphous nature of the glass system was validated by the presence of a broad hump in the XRD result. The refractive… read more here.
Keywords: optical basicity; glass; zinc borotellurite; basicity ... See more keywords
Synthesis of Mg-Doped Ordered Mesoporous Pd–Al2O3 with Different Basicity for CO, NO, and HC Elimination
Sign Up to like & getrecommendations! Published in 2017 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.6b03799
Abstract: Employing NH4HCO3 as pore-enlarging agent and P123 as a template agent, ordered mesoporous Mg-doped γ-Al2O3 with different basicity and large surface area have been successfully synthesized by a facile sol–gel approach by adjusting the content… read more here.
Keywords: surface area; different basicity; synthesis doped; al2o3 different ... See more keywords