Stable π Radical BDPA: Adsorption on Cu(100) and Survival of Spin
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DOI: 10.1002/cphc.202400852
Abstract: Abstract The adsorption of the radical α,ɣ‐bisdiphenylene‐β‐phenylallyl (BDPA) molecule to the Cu(100) surface was studied using scanning tunnelling microscopy (STM), scanning tunnelling spectroscopy (STS), and density functional theory (DFT) calculations accounting for dispersion forces. BDPA… read more here.
Keywords: radical bdpa; stable radical; bdpa; adsorption ... See more keywords
Water-soluble BDPA radicals with improved persistence.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc04920d
Abstract: 1,3-Bis(diphenylene)-2-phenylallyl (BDPA) radicals are promising polarizing agents for increasing the sensitivity of NMR spectroscopy through dynamic nuclear polarization (DNP), but have low persistence and solubility in aqueous media. New tetraalkyl/aryl-ammonium derivatives of BDPA are soluble… read more here.
Keywords: bdpa; water soluble; bdpa radicals; soluble bdpa ... See more keywords