Synthesis and Reactivity of Cobalt-Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen.
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DOI: 10.1021/acs.inorgchem.2c00234
Abstract: A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to… read more here.
Keywords: dinitrogen complexes; cobalt; bearing anionic; complexes bearing ... See more keywords