Synthesis and reactivity of PC(sp3)P-pincer iridium complexes bearing a diborylmethyl anion.
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DOI: 10.1039/d2dt00513a
Abstract: Novel PCP-pincer iridium complexes bearing a diborylmethyl anion were synthesized. Strong σ-electron-donation to the metal and significant π-backdonation from the metal to boron atoms at the β-position were observed both experimentally and computationally. H/D exchange… read more here.
Keywords: bearing diborylmethyl; pincer iridium; iridium complexes; complexes bearing ... See more keywords