On the Dynamic Behavior of Pacman Phosphanes─A Case of Cooperativity and Redox Isomerism.
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DOI: 10.1021/acs.inorgchem.3c00481
Abstract: In solution, the Pacman chlorophosphane (2Cl) shows fast exchange of the endo/exo-orientation of the two P-Cl bonds in the molecule featuring cooperativity. Experimental and quantum mechanical investigations of the inversion on the phosphorus(III) centers reveal… read more here.
Keywords: behavior pacman; dynamic behavior; redox isomerism; cooperativity ... See more keywords