Structure and redox behaviour of a paramagnetic Rh-Pt-Cu-Pt-Rh heterometallic-extended metal-atom chain.
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DOI: 10.1039/d4dt01134a
Abstract: A paramagnetic, pentanuclear, metal-metal bonded complex comprising three metals is isolated. The Cu dx2-y2 orbital of the Rh-Pt-Cu-Pt-Rh chain contains an unpaired electron. The close energetic levels and symmetric overlap of the Cu dx2-y2 and… read more here.
Keywords: redox behaviour; heterometallic extended; behaviour paramagnetic; structure redox ... See more keywords