Norbornadiene as a Building Block for the Synthesis of Linked Benzazocinones and Benzazocinium Salts through Tetranuclear Carbopalladated Intermediates
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DOI: 10.1021/acs.organomet.6b00795
Abstract: The six-membered C,N-palladacycle [Pd(C,N-C6H4CH2CMe2NH2-2)(μ-Cl)]2 (A) derived from phentermine reacts with norbornadiene to give a di- or tetranuclear complex arising from the double insertion of the same molecule of the strained alkene into one or two… read more here.
Keywords: norbornadiene building; tetranuclear complex; geometry; benzazocinones benzazocinium ... See more keywords