Hydrogen Peroxide Assisted Electrooxidation of Benzene to Phenol over Bifunctional Ni–(O–C2)4 Sites
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202204043
Abstract: Direct electrocatalytic oxidation of benzene has been regarded as a promising approach for achieving high‐value phenol product, but remaining a huge challenge. Here an oxygen‐coordinated nickel single‐atom catalyst (Ni–O–C) is reported with bifunctional electrocatalytic activities… read more here.
Keywords: hydrogen peroxide; benzene; assisted electrooxidation; electrooxidation benzene ... See more keywords
Poly(styrene–divinyl benzene)‐immobilized Fe(III) complex of 1,3‐bis(benzimidazolyl)benzene: Efficient catalyst for the photocatalytic degradation of xylenol orange
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.46480
Abstract: A polymer-supported Fe(III) complex of 1,3-bis(benzimidazolyl)benzene [PS–Fe(III)BBZNH] was used in the photodegradation of xylenol orange (XO) dye with H2O2 under UV irradiation. The catalyst was synthesized and characterized by elemental analysis, and Fourier transform infrared,… read more here.
Keywords: iii; complex bis; benzimidazolyl benzene; benzene ... See more keywords
Synthesis of benzene derivatives with multiple PCl2 groups.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300072
Abstract: The chlorination of 1,2-diphosphinobenzene with PCl5 to 1,2-bis(dichlorophosphino)benzene (2) was performed with high yields (93%) despite the high number of P-H functions. The method was further applied to other phosphanes, enabling the first synthesis and… read more here.
Keywords: benzene; dichlorophosphino benzene; multiple pcl2; derivatives multiple ... See more keywords
Production of Jet Fuel Range Aromatics by Alkylation of Benzene with Olefins over Bifunctional Ga/ZSM-5 Catalyst.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202401279
Abstract: Aromatic components of C8-C15 are playing indispensable roles in multi-functional properties of jet fuel. Here, we reported the controllable alkylation of benzene with mixed olefins of ethylene and propylene toward C8-C15 aromatic hydrocarbons for jet… read more here.
Keywords: catalyst; zsm catalyst; jet; alkylation ... See more keywords
Does the central nitrogen atom make a difference? A comparison of non‐coordinating pyridine and benzene spacers in multitopic ligands
Sign Up to like & getrecommendations! Published in 2024 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202400023
Abstract: In metal coordination compounds of the divergent ligands 4,2':6',4"‐terpyridine and 3,2':6',3"‐terpyridine and their 4'‐functionalized derivatives, the central pyridine ring of the 4,2':6',4"‐terpyridine and 3,2':6',3"‐terpyridine domains is non‐coordinated. We present an overview of data from the… read more here.
Keywords: benzene; terpyridine terpyridine; central nitrogen; terpyridine ... See more keywords
Residential ambient benzene exposure in the United States and subsequent risk of hematologic malignancies
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Cancer"
DOI: 10.1002/ijc.32202
Abstract: Benzene is considered a carcinogen, mostly based on evidence of causality for myeloid leukemia from high levels of exposure in occupational studies. We used United States Environmental Protection Agency National Ambient Toxics Assessment (NATA) estimates… read more here.
Keywords: ambient benzene; benzene; benzene exposure; risk hematologic ... See more keywords
Photochemical C−H Activation: An Early Story
Sign Up to like & getrecommendations! Published in 2017 at "Israel Journal of Chemistry"
DOI: 10.1002/ijch.201700046
Abstract: An early investigation in the author‘s laboratory into photochemical C−H bond activation and functionalization is recounted. Specifically, d8 Ir(I) and Rh(I) carbonyl phosphine complexes were found to promote benzene C−H bond activtion and functionalization to… read more here.
Keywords: photochemical activation; activation early; early story; benzene ... See more keywords
Multiple electronic state mechanism for carboryne reaction with benzene: A DFT study
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Quantum Chemistry"
DOI: 10.1002/qua.25372
Abstract: The multiple electronic state mechanisms of the reaction of carboryne with benzene were investigated by M11 calculations. Mechanisms leading to [4 + 2] cycloaddition product P4 + 2, [2 + 2] cycloaddition product P2 + 2, CC insert product PC-Cins and CH insert… read more here.
Keywords: multiple electronic; product; benzene; electronic state ... See more keywords
An Anion Pillared Metal-Organic Framework for Thermodynamic-Kinetic Synergistic Sieving of Benzene from Benzene/Cyclohexane Mixture.
Sign Up to like & getrecommendations! Published in 2025 at "Small"
DOI: 10.1002/smll.202506394
Abstract: Adsorption of benzene (Bz) is important to reduce environmental pollution and provide high-purity cyclohexane (Cy). However, the efficient separation of Bz and Cy still faces significant challenges because of their very similar molecular sizes and… read more here.
Keywords: organic framework; adsorption; cyclohexane; metal organic ... See more keywords
Down-regulation of miRNA-451a and miRNA-486-5p involved in benzene-induced inhibition on erythroid cell differentiation in vitro and in vivo
Sign Up to like & getrecommendations! Published in 2017 at "Archives of Toxicology"
DOI: 10.1007/s00204-017-2033-7
Abstract: Exposure to high-dose benzene leads to the inhibition of erythroid differentiation. However, whether lower doses of benzene exposure resemble high-dose effects in erythroid differentiation, as well as the underlying mechanisms, remains largely unknown. To identify… read more here.
Keywords: mirna 486; mirna 451a; 451a mirna; differentiation ... See more keywords
New benzene dimers: a benchmark theoretical investigation
Sign Up to like & getrecommendations! Published in 2020 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-020-02684-y
Abstract: A wide variety of methods have been used to study the retro-dimerization reactions of one cis-fused (1) and four new trans-fused benzene dimers (2–5). These methods, which included both single-reference and multi-reference approaches, were benchmarked… read more here.
Keywords: new benzene; kcal mol; reference; benzene ... See more keywords