Hydrogen Peroxide Assisted Electrooxidation of Benzene to Phenol over Bifunctional Ni–(O–C2)4 Sites
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Science"
DOI: 10.1002/advs.202204043
Abstract: Direct electrocatalytic oxidation of benzene has been regarded as a promising approach for achieving high‐value phenol product, but remaining a huge challenge. Here an oxygen‐coordinated nickel single‐atom catalyst (Ni–O–C) is reported with bifunctional electrocatalytic activities… read more here.
Keywords: hydrogen peroxide; benzene; assisted electrooxidation; electrooxidation benzene ... See more keywords
Poly(styrene–divinyl benzene)‐immobilized Fe(III) complex of 1,3‐bis(benzimidazolyl)benzene: Efficient catalyst for the photocatalytic degradation of xylenol orange
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.46480
Abstract: A polymer-supported Fe(III) complex of 1,3-bis(benzimidazolyl)benzene [PS–Fe(III)BBZNH] was used in the photodegradation of xylenol orange (XO) dye with H2O2 under UV irradiation. The catalyst was synthesized and characterized by elemental analysis, and Fourier transform infrared,… read more here.
Keywords: iii; complex bis; benzimidazolyl benzene; benzene ... See more keywords
Synthesis of benzene derivatives with multiple PCl2 groups.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300072
Abstract: The chlorination of 1,2-diphosphinobenzene with PCl5 to 1,2-bis(dichlorophosphino)benzene (2) was performed with high yields (93%) despite the high number of P-H functions. The method was further applied to other phosphanes, enabling the first synthesis and… read more here.
Keywords: benzene; dichlorophosphino benzene; multiple pcl2; derivatives multiple ... See more keywords
Residential ambient benzene exposure in the United States and subsequent risk of hematologic malignancies
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Cancer"
DOI: 10.1002/ijc.32202
Abstract: Benzene is considered a carcinogen, mostly based on evidence of causality for myeloid leukemia from high levels of exposure in occupational studies. We used United States Environmental Protection Agency National Ambient Toxics Assessment (NATA) estimates… read more here.
Keywords: ambient benzene; benzene; benzene exposure; risk hematologic ... See more keywords
Photochemical C−H Activation: An Early Story
Sign Up to like & getrecommendations! Published in 2017 at "Israel Journal of Chemistry"
DOI: 10.1002/ijch.201700046
Abstract: An early investigation in the author‘s laboratory into photochemical C−H bond activation and functionalization is recounted. Specifically, d8 Ir(I) and Rh(I) carbonyl phosphine complexes were found to promote benzene C−H bond activtion and functionalization to… read more here.
Keywords: photochemical activation; activation early; early story; benzene ... See more keywords
Multiple electronic state mechanism for carboryne reaction with benzene: A DFT study
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Quantum Chemistry"
DOI: 10.1002/qua.25372
Abstract: The multiple electronic state mechanisms of the reaction of carboryne with benzene were investigated by M11 calculations. Mechanisms leading to [4 + 2] cycloaddition product P4 + 2, [2 + 2] cycloaddition product P2 + 2, CC insert product PC-Cins and CH insert… read more here.
Keywords: multiple electronic; product; benzene; electronic state ... See more keywords
Down-regulation of miRNA-451a and miRNA-486-5p involved in benzene-induced inhibition on erythroid cell differentiation in vitro and in vivo
Sign Up to like & getrecommendations! Published in 2017 at "Archives of Toxicology"
DOI: 10.1007/s00204-017-2033-7
Abstract: Exposure to high-dose benzene leads to the inhibition of erythroid differentiation. However, whether lower doses of benzene exposure resemble high-dose effects in erythroid differentiation, as well as the underlying mechanisms, remains largely unknown. To identify… read more here.
Keywords: mirna 486; mirna 451a; 451a mirna; differentiation ... See more keywords
New benzene dimers: a benchmark theoretical investigation
Sign Up to like & getrecommendations! Published in 2020 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-020-02684-y
Abstract: A wide variety of methods have been used to study the retro-dimerization reactions of one cis-fused (1) and four new trans-fused benzene dimers (2–5). These methods, which included both single-reference and multi-reference approaches, were benchmarked… read more here.
Keywords: new benzene; kcal mol; reference; benzene ... See more keywords
Titanium-benzene complex as a molecular oxide adsorbent: a first principles approach
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-021-04869-z
Abstract: CO, SO, NO, CO2, SO2, and NO2 gas sensing properties of Ti-benzene (C6H6Ti) complex are studied with first principles calculations by analyzing change in structural parameters, electronic properties, and charge transfer. Adsorption of all six… read more here.
Keywords: titanium benzene; complex molecular; benzene complex; oxide molecules ... See more keywords
Direct Amination of Benzene with NH3 and H2O2 Over Hierarchical Fe,Cu/ZSM-5 Prepared by Post-synthesis Treatment of Nanocrystallite B–ZSM-5
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Letters"
DOI: 10.1007/s10562-019-03026-9
Abstract: Hierarchical Fe,Cu/ZSM-5 was prepared by post-synthesis treatment of nanocrystallite B–ZSM-5. The hierarchical MFI zeolites containing Fe and/or Cu were characterized with XRD, FT-IR, SEM, UV–Vis and N2-sorption techniques. UV–Vis and FT-IR spectroscopy demonstrated that some… read more here.
Keywords: direct amination; zsm prepared; benzene; amination ... See more keywords
Optimization of non-thermal plasma efficiency in the simultaneous elimination of benzene, toluene, ethyl-benzene, and xylene from polluted airstreams using response surface methodology
Sign Up to like & getrecommendations! Published in 2017 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-017-0373-8
Abstract: Treatment with a non-thermal plasma (NTP) is a new and effective technology applied recently for conversion of gases for air pollution control. This research was initiated to optimize the efficient application of the NTP process… read more here.
Keywords: methodology; thermal plasma; response; non thermal ... See more keywords