De novo Assembly of the Benzenoid Ring as a Core Strategy for Synthesis of the Isoindolinone Natural Products Isohericerin, Erinacerin A, and Sterenin A.
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DOI: 10.1021/acs.orglett.1c02752
Abstract: Here we describe the use of the hexadehydro-Diels-Alder (HDDA) reaction for the de novo construction of the isoindolinone scaffold and its application to the synthesis of the title natural products. The key isoindolinone-forming HDDA reaction… read more here.
Keywords: novo assembly; natural products; benzenoid ring; isoindolinone ... See more keywords