Synthesis of highly branched polyethylene using para-benzhydryl substituted iminopyridyl Ni(II) and Pd(II) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.11.024
Abstract: Abstract A series of para-benzhydryl substituted iminopyridyl-based Ni(II) and Pd(II) complexes with systematically varied ligand steric, [2,6-R2-4-CHPh2C6H2N = CH(NC6H5)]MX2 (MX2 = NiBr2 or PdCl2; R = -CHPh2 (Ni1,Pd1); R = iPr (Ni2,Pd2); R = Et (Ni3,Pd3); R = Me (Ni4,Pd4)], were synthesized and applied to ethylene oligo-/polymerization… read more here.
Keywords: benzhydryl substituted; para benzhydryl; branched polyethylene; highly branched ... See more keywords
Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03798
Abstract: A transition-metal-free protocol for the arylation of N-phenyl- and N-benzoyl-substituted, benzaldehyde-derived imine derivatives with functionalized aryl pronucleophiles is reported. The aryl nucleophiles are released from silicon-protected aryl-substituted diazenes by desilylation with potassium trimethylsilanolate concomitant with… read more here.
Keywords: synthesis benzhydryl; functionalized aryl; aryl nucleophiles; benzhydryl substituted ... See more keywords