Correlating Structural Features and 207Pb NMR Parameters with the Stereochemical Activity of PbII Lone Pairs in Birefringent Pb[2,6-bis(benzimidazol-2-yl)pyridine] Complexes
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DOI: 10.1002/ejic.201601235
Abstract: A series of PbII materials containing the highly anisotropic tridentate ligand 2,6-bis(benzimidazol-2-yl)pyridine (bbp) and [Au(CN)2]–, Hg(CN)2 or halide bridging units, [Pb(bbp)Br2]·2H2O, Pb(bbp)I2, [Pb(bbp)I]2(µ-I)[Au(CN)2], [Pb(bbp)Br]2(µ-Br)[Au(CN)2], [Pb(bbp)Br2][Hg(CN)2], Pb(bbp)Cl[Au(CN)2]·0.25H2O and Pb(H2O)(bbp)2[Au(CN)2]2, have been prepared, structurally characterised and investigated… read more here.
Keywords: lone; bis benzimidazol; bbp; stereochemical activity ... See more keywords
Synthesis of bimetallic complexes bridged by 2,6-bis(benzimidazol-2-yl) pyridine derivatives and their catalytic properties in transfer hydrogenation.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03178a
Abstract: A series of binuclear rhodium(i) and iridium(i) complexes with 2,6-bis(benzimidazol-2-yl) pyridine (bzimpy) derivatives were synthesized and characterized by elemental analysis and spectroscopic methods. The molecular and crystal structures of complex 3d were determined by the… read more here.
Keywords: transfer hydrogenation; bis benzimidazol; bimetallic complexes; benzimidazol pyridine ... See more keywords
A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane
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DOI: 10.1055/a-1527-4526
Abstract: The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C–Cl bonds are effectively converted into C–H bonds using an [IrCl(cod)]2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the… read more here.
Keywords: catalyst; reduction alkyl; benzimidazol pyridine; bis benzimidazol ... See more keywords