Multidimensional networks constructed with 2,5-dichloroterephthalate and bis(benzimidazole) co-ligands: Syntheses, structures, electrochemical and photocatalytic properties
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DOI: 10.1016/j.poly.2017.05.022
Abstract: Abstract A halogenated linear bridged dicarboxylic acid ligand, 2,5-dichloroterephthalic acid (H2DCTP), was used to construct three coordination polymers (CPs) with Mn(II) salts in the presence of different bis(benzimidazole) N-containing co-ligands: 1,2-bis(2-methylbenzimidazol-1-ylmethyl)benzene (L1), 1,4-bis(5,6-dimethylbenzimidazole)butane (L2) and… read more here.
Keywords: multidimensional networks; networks constructed; bis; bis benzimidazole ... See more keywords
{Ru(CO)x}-Core complexes with benzimidazole ligands: synthesis, X-ray structure and evaluation of anticancer activity in vivo.
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DOI: 10.1039/c6dt04295c
Abstract: The reaction of [Ru(CO)6Cl2], 1, with N[combining low line]3-methylbenzimidazole (MBI) and 5,6-dimethylbenzimidazole (DMBI) afforded two new complexes with the general formula fac-[RuII(CO)3Cl2L], L = MBI (2) or DMBI (4). Crystals of cis,trans-[RuII(CO)2Cl2(N[combining low line]3-MBI)2], 3,… read more here.
Keywords: ligands synthesis; complexes benzimidazole; core complexes; synthesis ray ... See more keywords
Tailoring the π-system of benzimidazole ligands towards stable light-harvesting cyclometalated iridium(III) complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00200d
Abstract: The synthesis, structure, optical and redox properties as well as photovoltaic studies of iridium(III) complexes with cyclometalated 2-arylbenzimidazoles decorated with various polyaromatic fragments and an ancillary aromatic β-diketone are reported. Despite the strong preference of… read more here.
Keywords: benzimidazole ligands; iridium iii; iridium; iii complexes ... See more keywords