Photocatalyzed Nitrene Insertion into C-O Bonds: Access to Benzisoxazoline-3-ones.
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DOI: 10.1021/acs.orglett.5c04188
Abstract: The first photoinduced formal nitrene insertion into C-O bonds is established with sulfilimines as free nitrene precursors, providing facile access to N-substituted benzisoxazoline-3-ones under mild and additive-free conditions. DFT calculations indicate a mechanism proceeding via… read more here.
Keywords: nitrene insertion; access; photocatalyzed nitrene; benzisoxazoline ones ... See more keywords