Articles with "benzofused heterocycles" as a keyword



Photo by jernejgraj from unsplash

Synthesis of Benzofused O- and N-Heterocycles through Cascade Carbopalladation/Cross-Alkylation of Alkynes Involving the C–C Cleavage of Cyclobutanols

Sign Up to like & get
recommendations!
Published in 2022 at "Organometallics"

DOI: 10.1021/acs.organomet.2c00015

Abstract: We report a Pd-catalyzed route to heterocycles bearing a tetrasubstituted alkene fragment. Our approach merges the intramolecular carbopalladation of tethered alkynes with an alkylation step produced by the C–C cleavage of cyclobutanol derivatives. An alkenyl-Pd(II)… read more here.

Keywords: cleavage; benzofused heterocycles; synthesis benzofused; cascade carbopalladation ... See more keywords
Photo by imkirk from unsplash

Synthesis of Benzofused N-Heterocycles via Rh(III)-Catalyzed Direct Benzannulation with 1,3-Dienes

Sign Up to like & get
recommendations!
Published in 2018 at "ACS Catalysis"

DOI: 10.1021/acscatal.8b03595

Abstract: Benzofused nitrogen heterocycles are prevalent as key core structural motifs in functional molecules. Major syntheses of benzofused nitrogen heterocycles focus on construction of the heterocyclic ring starting from (poly)substituted benzene derivatives. Given that polysubstituted benzene… read more here.

Keywords: direct benzannulation; synthesis benzofused; benzofused heterocycles; catalyzed direct ... See more keywords