The importance of four‐membered NHCs in stabilizing Breslow intermediates on benzoin condensation pathway
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DOI: 10.1002/jcc.26935
Abstract: N‐heterocyclic carbenes (NHCs) have been established to be effective organocatalysts for facilitating the benzoin condensation and many other reactions. These reactions involve the formation of a Breslow intermediate (BI), which exhibits umpolung chemistry. To facilitate… read more here.
Keywords: reaction; membered nhcs; chemistry; four membered ... See more keywords