B(C6F5)3-Catalyzed Reductive Denitrogenation of Benzonitrile Derivatives.
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DOI: 10.1021/acs.orglett.2c01003
Abstract: A B(C6F5)3-catalyzed reductive denitrogenation of aromatic nitriles is reported, achieving the metal-free transformation of a cyano into a methyl group in a single synthetic operation. Tris(phenylsilyl)amine is liberated as the nitrogen-containing byproduct. On the basis… read more here.
Keywords: denitrogenation benzonitrile; reductive denitrogenation; c6f5 catalyzed; benzonitrile derivatives ... See more keywords